Summary:
This book looks at new ways of tackling the problem of separating reaction products from homogeneous catalytic solutions. The new processes involve low leaching supported catalysts, soluble supports such as polymers and dendrimers and unusual solvents such as water, fluorinated organics, ionic liquids and supercritical fluids. The advantages of the different possibilities are discussed alongside suggestions for further research that will be required for commercialisation. Unlike other books, in addition to the chemistry involved, the book looks at the process design that would be required to bring the new approaches to fruition. Comparisons are given with existing processes that have already been successfully applied and examples are given where these approaches are not suitable." This book is an invaluable resource for industrialists in the chemical and pharmaceutical industries, particularly those involved with improving environmental impact of current or future processes. It is also a useful resource for academics who wish to apply homogeneous catalysis to solving real problems and for advanced undergraduate and postgraduate courses in catalysis.
Table of Contents
Ch. 1 Homogeneous catalysis - advantages and problems 1
Ch. 2 Classical homogeneous catalyst separation technology 9
Ch. 3 Supported catalysts 39
Ch. 4 Separation by size-exclusion filtration 73
Ch. 5 Biphasic systems : water - organic 105
Ch. 6 Fluorous biphasic catalysis 145
Ch. 7 Catalyst recycling using ionic liquids 183
Ch. 8 Supercritical fluids 215
Ch. 9 Areas for further research 237

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