📌 🔒 Catalysts

Industrial Catalysis: A Practical Approach

2006Wiley Industrial Catalysis: A Practical Approach

ISBN: 3527311440

Title: Industrial Catalysis: A Practical Approach

Author: Jens Hagen

Publisher: John Wiley & Sons

Publication Date: 2006-03-03

Number Of Pages: 526

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Asymmetric Catalysis on Industrial Scale



Asymmetric Catalysis on Industrial Scale

ISBN: 3527306315

Title: Asymmetric Catalysis on Industrial Scale: Challenges, Approaches and Solutions (Chemistry)

Author:

Publisher: John Wiley & Sons

Publication Date: 2004-01-16

Number Of Pages: 480

Product Details

Hardcover: 480 pages

Publisher: John Wiley & Sons Canada, Ltd.; 1 edition (Dec 8 2003)

ISBN: 3527306315

Amazon.ca Sales Rank: #753,431 in Books

Table of Contents

List of Contributors.

Introduction (Hans-Ulrich Blaser & Elke Schmidt).

I: NEW PROCESSES For EXISTING ACTIVE COMPOUNDS.

1. Asymmetric Hydrogenations— The Monsanto L-Dopa Process (William S. Knowles).

2. The Other L-Dopa Process (Rüdiger Selke).

3. The Chiral Switch of Metolachlor: The Development of a Large-Scale Enantioselective Catalytic Process (Hans-Ulrich Blaser, et al.).

4. Enantioselective Hydrogenation: Towards a Large-Scale Total Synthesis of (R,R,R)-a-Tocopherol (Thomas Netscher, et al.).

5. Comparison of Four Technical Synthesis of Ethyl ®-2-Hydroxy-4-Phenylbutrate (Hans-Ulrich Blaser, et al.).

6. Biocatalytic Approaches for the Large-Scale Production of Asymmetric Synthons (Nicholas M. Shaw, et al.).

7. 7-Aminocephalosporanic Acid-Chemical Versus Enzymatic Production Process (Thomas Bayer).

8. Methods for the Enantioselective Biocatalytic Pro duction of L-Amino Acids on an Industrial Scale (Harald Gröger & Karlheinz Drauz).

II: NEW CATALYSTS For EXISTING ACTIVE COMPOUNDS.

1. The Large-Scale Biocatalytic Synthesis of Enantiopure Cyanohydrins (Peter Poechlauer, et al.).

2. Industrialization Studies of the Jacobsen-Hydrolytic Kinetic Resolution of Epichlorohydrin (Larbi Aouni, et al.).

3. Scale-up Studies in Asymmetric Transfer Hydrogenation (John Blacker & Juliette Martin).

4. Practical Applications of Biocatalysis for the Manufacture of Chiral Alcohols such as ®-1,3-Butanediol by Stereospecific Oxidoreduction (Akinobu Matsuyama & Hiroaki Yamamoto).

5. Production of Chiral C3 and C4 Units via Microbial Resolution of 2,3-Dichloro-1-propanol, 3-Chloro-1,2-propanediol and Related Halohydrins (N. Kasai o& T. Suzuki).

III: ADAPTATION OF EXISTING CATALYSTS For IMPORTANT BUILDING BLOCK.

1. Synthesis of Unnatural Amino Acids (David J. Ager & Scott A. Laneman.).

2. The Application of DuPHOS Rhodium(I) Catalysts for Commercial Scale Asymmetric Hydrogenation (Christopher J. Cobley, et al.).

3. Liberties and Constraints in the Development of Asymmetric Hydrogenations on a Technical Scale (John F. McGarrity, et al.).

4. Large-Scale Applications of Biocatalysis in the Asymmetric Synthesis of Laboratory Chemicals (Roland Wohlgemuth).

IV: PROCESSES For NEW CHEMICAL ENTITIES (NCE).

1. Development of an Efficient Synthesis of Chiral 2-Hydroxy Acids (Junhua Tao & Kevin McGee).

2. Factors Influencing the Application of Literature Methods Toward the Preparation of a Chiral trans-Cyclopropane Carboxylic Acid Intermediate During Development of a Melatonin Agonist (Ambarish K. Singh, et al.).

3. Hetero Diels-Alder-Biocatalysis Approach for the Synthesis of (S)-3-[2-{(Methylsulfonyl)oxy}ethoxy]-4-(triphenylmethoxy)-1-butanol Methanesulfonate: Successful Application of an Enzyme Resolution Process (Jean-Claude Caille, et al.).

4. Multi-Kilo Resolution of XU305, a Key Intermediate to the Platelet Glycoprotein IIb/IIIa Receptor Antagonist Roxifiban Via Kinetic and Dynamic Enzymatic Resolution (Jaan A. Pesti & Luigi Anzalone).

5. Protease-Catalyzed Preparation of (S)-2-[(tert-Butylsulfonyl)methyl]-hydrocinnamic Acid for Renin Inhibitor RO0425892 (Beat Wirz, et al.).

6. Protease-Catalyzed Preparation of Chiral 2-Isobutyl Succinic Acid Derivatives for Collagenase Inhibitor RO0319790 (Beat Wirz, et al.).

7. An Innovative Asymmetric Sulfide Oxidation: The Process Development History Behind the New Antiulcer Agent Esomeprazole (Hans-Jürgen Federsel & Magnus Larsson).

8. Development of a Biocatalytic Process for the Resolution of ®- and (S)-Ethyl-3-amino-4-pentynoate Isomers Using Enzyme Penicillin G Amidohydrolase (Ravindra S. Topgi).

Subject Index.

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Heterocyclic Carbenes in Transition Metal Catalysis



N-heterocyclic carbenes, singlet carbenes with the carbene being incorporated in a nitrogen-containing heterocycle, were first investigated byWanzlick in the early 1960s [3]. Shortly thereafter, the first application of NHC as a ligand for metal complexes was independently described by Wanzlick [4] and Öfele [5] in 1968. Nevertheless, the field of N-heterocyclic carbenes as ligands in transition metal chemistry remained dormant until 1991 when a report on the extraordinary stability, isolation and storability of crystalline NHC IAd by Arduengo et al. ignited a rapidly growing research field.

Front Matter

1 N-Heterocyclic Carbenes in Catalysis—An Introduction

2 N-Heterocyclic Carbenes as Ligands for High-Oxidation-State Metal Complexes and Oxidation Catalysis

3 Palladium-catalyzed Reactions Using NHC Ligands

4 Routes to N-Heterocyclic Carbene Complexes

5 Chiral N-Heterocyclic Carbenes as Stereodirecting Ligands in Asymmetric Catalysis

6 Transition Metal-Catalyzed Reactions Using N-Heterocyclic Carbene Ligands (Besides Pd- and Ru-Catalyzed Reactions)

7 N-Heterocyclic Carbenes as Ligands for Olefin Metathesis Catalysts

Back Matter

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Synthesis of Heterocycles via Palladium-Catalyzed Oxidative Addition

Synthesis of Heterocycles via Palladium-Catalyzed Oxidative Addition

Synthesis of Heterocycles via Palladium-Catalyzed Oxidative Addition

1. Introduction

2. Palladium Chemistry. General Comments

3. Heterocycles via Palladium-Catalyzed Oxidative Addition Reactions. General Comments

4. Heterocycles via Alkene Cyclizations

4.1. Heterocycles via Intramolecular Heck Cyclization of Aryl Halides

4.2. Heterocycles via Intramolecular Heck Cyclization of Vinylic Halides

4.3. Heterocycles via Intramolecular Heck Cyclization of Vinylic and Aryl Triflates

4.4. Heterocycles via Intermolecular Annulation

4.5. Heterocycles via Asymmetric Heck Cyclization

4.6. Heterocycles by the Annulation of Dienes

4.6.1. Heterocycles by the Annulation of 1,2-Dienes

4.6.2. Heterocycles via Cyclization of 1,3-Dienes

4.6.3. Heterocycles via Cyclization of 1,4-Dienes

5. Heterocycles via Cyclization and Annulation of Alkynes

5.1. Heterocycles via Cyclization and Annulation of Internal Alkynes

5.2. Heterocycles via Cyclization of Terminal Alkynes

5.3. Heterocycles via Cyclization of Alkynes plus CO

6. Heterocycles via Carbonylative Cyclization

6.1. Heterocycles via Carbonylative Cyclization of Aryl Halides

6.2. Heterocycles via Carbonylative Cyclization of Vinylic Halides

7. Heterocycles via Palladium-Catalyzed Aryl/Vinylic Amination. Hartwing-Buchwald C-N Bond Formation

8. Heterocycles via Palladium-Catalyzed

Intramolecular Biaryl Cross-Coupling

9. Conclusion

10. Acknowledgments

11. References



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Aqueous-Phase Organometallic Catalysis: Concepts and Applications

Aqueous-Phase Organometallic Catalysis: Concepts and Applications

ISBN: 3527307125

Title: Aqueous-Phase Organometallic Catalysis: Concepts and Applications

Author: Boy Cornils (Editor), Wolfgang A. Herrmann (Editor)

Publisher: John Wiley & Sons

Publication Date: 2004-04-29

Number Of Pages: 780

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Aqueous-Phase Organometallic Catalysis: Concepts and Applications, 2nd, Completely Revised and Enlarged Edition

Boy Cornils (Editor), Wolfgang A. Herrmann (Editor)

ISBN: 3-527-30712-5

Hardcover

780 pages

Now in its second completely revised and expanded edition. Written by the renowned editors B. Cornils and W. A. Herrmann, this book presents every important aspect of aqueous-phase organometallic catalysis, a method which saves time, waste and money. The large-scale application of this "green" technology in chemical industry clearly underlines its practical use outside of academia.

New chapters (for example "Organic Chemistry in Water"), 20% more content and fully updated contributions from by a plethora of international authors make this book a "must-have" for everyone working in this field.

from the reviews of the first edition:

"This overview will be extremely useful for everyone active in this field [...]" Angewandte Chemie

"This book is an essential in any chemical research library and I strongly recommend it to all synthetic research and teaching chemists. [...]" The Alchemist

"The editors are to be congratulated on assembling such a wide range of contributors who have described the industrial as well as the academic aspects of the subject." [...] Journal of Organometallic Chemistry

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Catalysis and Electrocatalysis at Nanoparticle Surfaces

Catalysis and Electrocatalysis at Nanoparticle Surfaces



ISBN: 🔒 Bấm Cảm ơn hoặc Trả lời để xem SĐT/Liên hệ

Title: Catalysis and Electrocatalysis at Nanoparticle Surfaces

Author: Andrzej Wieckowski (Editor), Elena R. Savinova (Editor), Constantinos G. Vayenas (Editor)

Publisher: CRC

Publication Date: 2003-02-19

Number Of Pages: 970

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Catalyzing Inquiry at the Interface of Computing And Biology(2005)



Catalyzing Inquiry at the Interface of Computing And Biology(2005)

Catalyzing Inquiry at the Interface of Computing And Biology

Author: National Research Council (U. S.)

Publisher: National Academies Press

Publication Date: 2005-11

Number Of Pages: 443

Description

The remarkable growth of both computer science and biology in recent decades has drawn attention to their areas of intersection. Both fields have much in common; they are among the most rapidly changing fields of science, they both deal with very complex systems, and they both have profound implications for science and society. To examine the potential for greater interaction between the two fields, the National Research Council undertook a study looking at ways computational science can aid the development and understanding of biology and how the biological sciences might facilitate new and more powerful computational methods. This book presents an analysis of the potential synergies at the interface of the two fields and of ways to develop new collaborations between researchers in both areas to exploit those synergies. The book provides a large sample of well-documented examples of these interactions. The study concludes that the impact of computing on biology will be deep and profound and span virtually all areas of life science research. Computational biology will ultimately become part of the biological

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Polymeric Materials in Organic Synthesis and Catalysis



Polymeric Materials in Organic Synthesis and Catalysis

Book Properties

ISBN: 3527306307

Title: Polymeric Materials in Organic Synthesis and Catalysis

Author: Michael R. Buchmeiser

Publisher: John Wiley & Sons

Publication Date: 2003-09-26

Number Of Pages: 582

This is the first book to describe the synthesis and characterization of the materials used in polymer-supported synthesis. The authors cover not only the classical polymers and their use in homogeneous, heterogeneous and micellar catalysis, but also such new developments as "enzyme-labile linkers", illustrating how to simplify the purification process and avoid waste. The result is a wealth of useful information -- for beginners and experts alike - in one handy reference, removing the need for difficult and time-consuming research among the literature.

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Interfacial Catalysis



Interfacial Catalysis

ISBN: 🔒 Bấm Cảm ơn hoặc Trả lời để xem SĐT/Liên hệ

Title: Interfacial Catalysis

Author: Alexander G. Volkov

Publisher: CRC

Publication Date: 2002-12-12

Number Of Pages: 680

Editorial Description

A comprehensive volume on interfacial catalysis, this book includes contributions from an international group of specialists in chemistry, environmental science, informatics, physiology, nuclear energy, and physics. The editor has organized the material into the main topics of fundamental characteristics, phase transfer catalysis, reversed micelles, biological aspects, and interfacial photocatalysis. Individual topics include self-organized microheterogeneous structures, nanochemistry, interfaci ...read whole description

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Transition Metal Reagents and Catalysts

Transition Metal Reagents and Catalysts （willey）

Title: Transition Metal Reagents and Catalysts

Front Matter (p i-xv)

1. Pioneering Industrial Processes Using Homogeneous Transition Metal Catalysts

(p 1-6)

2. Basic Chemistry of Transition Metal Complexes and Their Reaction Patterns (p 7-26) 3. Reactions of Organic Halides and Pseudohalides (p 27-108)

4. Reactions of Allylic Compounds (p 109-168)

5. Reactions of Propargylic Compounds (p 199-226)

6. Reactions of Alkenes and Alkynes (p 227-303)

7. Synthetic Reactions Via Transition Metal Carbene Complexes (p 305-354)

8. Protection and Activation by Coordination (p 355-392)

9. Catalytic Hydrogenation, Transfer Hydrogenation and Hydrosilylation (p 393-417)

10. Reactions Promoted and Catalysed by Pd(II) Compounds (p 419-455)

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Concepts of Modern Catalysis and Kinetics

Book Properties

ISBN: 3527305742

Title: Concepts of Modern Catalysis and Kinetics

Author: I. Chorkendorff J. W. Niemantsverdriet

Publisher: John Wiley & Sons

Publication Date: 2003-12-30

Number Of Pages: 469

Introduction:

Until now, the literature has offered a rather limited approach to the use of fundamental kinetics and their application to catalytic reactions. Subsequently, this book spans the full range from fundamentals of kinetics and heterogeneous catalysis via modern experimental and theoretical results of model studies to their equivalent large-scale industrial production processes. The result is key knowledge for students at technical universities and professionals already working in industry.

'... such an enterprise will be of great value to the community, to professionals as well as graduate and undergraduate students attempting to move into the field of modern catalysis and kinetics. I strongly recommend you publish this book based on the proposal.' - Prof. Dr. G. A. Samorjai, University of California

'Both authors are well respected specialists, with a very long record of original top-quality work and an international reputation. A book from these authors will be considered an authoritative piece of work, I definitely support this project and I am looking forward to use the book when published.' - Prof. Dr. D. E. Resasco, University of Oklahoma

'I wholly support the proposed project. The authors are very competent young colleagues and there is a real need for such a textbook' - Prof. Dr. G. Ertl, Fritz-Haber-Institut, Max-Planck-Gesellschaft, Berlin

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Topics in Current Chemistry, 276, In situ NMR Methods in Catalysis



Publisher: Springer

Number Of Pages:

Publication Date: 2007-06-27

Sales Rank: 3383874

ISBN / ASIN: 354071426X

EAN: 9783540714262

Binding: Hardcover

Manufacturer: Springer

Studio: Springer

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New Frontiers in Asymmetric Catalysis



Publisher: Wiley-Interscience

Number Of Pages: 418

Publication Date: 2007-05-04

Sales Rank: 1210442

ISBN / ASIN: 🔒 Bấm Cảm ơn hoặc Trả lời để xem SĐT/Liên hệ

EAN: 9780471680260

Binding: Hardcover

Manufacturer: Wiley-Interscience

Studio: Wiley-Interscience



A compilation of recent advances and applications in asymmetric catalysis

The field of asymmetric catalysis has grown rapidly and plays a key role in drug discovery and pharmaceuticals. New Frontiers in Asymmetric Catalysis gives readers a fundamental understanding of the concepts and applications of asymmetric catalysis reactions and discusses the latest developments and findings. With contributions from preeminent scientists in their respective fields, it covers:

"Rational" ligand design, which is critically dependent on the reaction type (reduction, oxidation, and C-C bond formation)

Recent findings on activation of C-H bonds, C-C bonds, and small molecules (C=O, HCN, RN=C, and CO2) and the latest developments on C-C bond reorganization, such as metathesis

Advances in "chirally economical" non-linear phenomena, racemic catalysis, and autocatalysis

Some of the recent discoveries that have led to a renaissance in the field of organocatalysis, including the development of chiral Brönstead acids and Lewis acidic metals bearing the conjugate base of the Brönstead acids as the ligands and the chiral bi-functional acid/base catalysts

The book ends with a thought-provoking perspective on the future of asymmetric catalysis that addresses both the challenges and the unlimited potential in this burgeoning field. This is an authoritative, up-to-date reference for organic chemists in academia, government, and industries, including pharmaceuticals, biotech, fine chemicals, polymers, and agriculture. It is also an excellent textbook for graduate students studying advanced organic chemistry or chemical synthesis.



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Dendrimer Catalysis (Topics in Organometallic Chemistry)



Publisher: Springer

Number Of Pages: 189

Publication Date: 2006-10-05

Sales Rank: 3882320

ISBN / ASIN: 3540344748

EAN: 9783540344742

Binding: Hardcover

Manufacturer: Springer

Studio: Springer

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Catalytic Antibodies



Publisher: Wiley-VCH

Number Of Pages: 616

Publication Date: 2005-01-04

Sales Rank: 2167235

ISBN / ASIN: 3527306889

EAN: 9783527306886

Binding: Hardcover

Manufacturer: Wiley-VCH

Studio: Wiley-VCH

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Book Description:

Exploiting the inherent combinatorial mechanism in the biosynthesis of antibodies, an almost limitless variety of biocatalysts may be generated. Catalytic antibodies are capable of performing almost any type of reaction with high selectivity and stereospecificity.

Here, the pioneers in the use of catalytic antibodies review the entire scope of this interdisciplinary field, covering such topics as:

theoretical aspects of structure, mechanism and kinetics

practical considerations, from immunization techniques to screening methods

in vitro evolution and other modern approaches

applications from organic synthesis to medical uses.

Backed by the leading authorities in antibody catalysis, this is the first book to provide such comprehensive coverage and will be the prime reference for biochemists, organic chemists, biotechnologists and biomedical researchers.

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Stereoselective Biocatalysis



Stereoselective Biocatalysis

By Ramesh N. Patel

Publisher: CRC

Number Of Pages: 946

Publication Date: 2000-01-03

Sales Rank: 2740931

ISBN / ASIN: 🔒 Bấm Cảm ơn hoặc Trả lời để xem SĐT/Liên hệ

EAN: 9780824782825

Binding: Hardcover

Manufacturer: CRC

Studio: CRC

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Book Description:

An explanation of the specific ways that biocatalysis outperforms chemical catalysis by: utilizing ambient temperature and atmospheric pressure to minimize problems of isomerization, racemization, and epimerization; employing microbial cells and enzymes that can be immobilized and reused over many cycles; and overexpressing enzymes for greater economy and efficiency.

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In-Situ Spectroscopy in Heterogeneous Catalysis



Publisher: Wiley-VCH

Number Of Pages: 288

Publication Date: 2002-07-09

Sales Rank: 1701239

ISBN / ASIN: 3527302484

EAN: 9783527302482

Binding: Hardcover

Manufacturer: Wiley-VCH

Studio: Wiley-VCH

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Book Description:

"Not using in-situ methods to examine catalytic processes is like studying a life with access only to the prenatal and postmortem states." This quote from the world renowned specialist in the field of in situ methods, read.freeduan.com Gabor A. Somorjai, clearly emphasizes the importance of these techniques in understanding heterogeneous catalysis - a type of chemical reaction used nowadays for most chemically produced supplies and fuels. Yet the fundamental mechanisms are often still not completely understood.

Many of the leading scientists in the field have contributed to this book which provides an overview of the most varied spectroscopic and related methods for studying catalytic structures and their functions during a chemical reaction. While primarily written for users of these methods, this is also a valuable aid to interpreting the phenomena observed. Indispensable for everyone working in the field.

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Nanocatalysis (NanoScience and Technology)



Publisher: Springer

Number Of Pages: 503

Publication Date: 2006-11-16

Sales Rank: 667079

ISBN / ASIN: 3540326456

EAN: 9783540326458

Binding: Hardcover

Manufacturer: Springer

Studio: Springer

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Book Description: )

Nanocatalysis is one of the most exciting subfields to have emerged from nanoscience. Its central aim is the control of chemical reactions by changing the size, dimensionality, chemical composition and morphology of the reaction center and by changing the kinetics using nanopatterning of the reaction centers. This approach opens up new avenues for atom-by-atom design of nanocatalysts with distinct and tunable chemical activity, specificity, and selectivity. This book is intended to give a pedagogical and methodological overview of this exciting and growing field and to highlight specific examples of current research. In this way, it serves both as an instructive introduction for graduate students who plan to enter the field and as a reference work for scientists already active in this and related areas.

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Introduction to Surface Chemistry and Catalysis



Introduction to Surface Chemistry and Catalysis

Introduction to Surface Chemistry and Catalysis

* Publisher: John Wiley & Sons

* Number Of Pages: 696

* Publication Date: 1994-03-04

* Sales Rank: 647446

* ISBN / ASIN: 🔒 Bấm Cảm ơn hoặc Trả lời để xem SĐT/Liên hệ

* EAN: 9780471031925

* Binding: Hardcover

* Manufacturer: John Wiley & Sons

* Studio: John Wiley & Sons

* Average Rating: 4.5

* Total Reviews: 3

Book Description: )

Describes the present state of modern surface science, and is also a reference source for data and concepts related to properties of surfaces and interfaces. Focuses on the qualities of solid-gas and solid-vacuum interfaces. Discusses local attributes of surface atoms and molecules, atomic structures, chemical bonding, absorptions, catalysis and mechanical properties. Presents molecular understanding of surface phenomena and relates it to macroscopic surface properties.

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The catalytic oxidation of organic compounds in the vapor phase

The catalytic oxidation of organic compounds in the vapor phase

ISBN: B0006ALY4U

Title: The catalytic oxidation of organic compounds in the vapor phase, (American chemical society. Monograph series)

Author: L. F Marek

Publisher: The Chemical catalog company, inc

Publication Date: 1932

Number Of Pages: 486

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